Inorganic Chemistry Research Laboratory II

About

Research Infrastructure

• Thermogravimetric/Differential Thermal analysis (Shimadzu DTG-60H)
• Differential Scanning Calorimetry Device (Shimadzu DSC-60)
• UV-3600 UV-VIS-NIR Spectrophotometer
• Parr 5500 High Pressure Reactor
• High Temperature Tube Furnace
• Vacuum Oven
• Rotary Evaporator

Researchers

•    Prof. Dr. Birgül KARAN
•    Prof. Dr. Ahmet Nedim Ay
•    Öğr. Gör. Dr. Okan İçten
•    Yüksek lisans öğrencisi Abdurrahman Mete Turgut
•    Doktora Öğrencisi, Ömer Yurdakul

Ongoing Projects

• “Development of Nano-Manganese Oxyborate Synthesis for Energy-Oriented Applications”, Comprehensive Research Project (2018-30-06-30-005), Supporting Organization: TENMAK-BOREN (National Boron Research Institute). prof. Dr. Birgül Karan (Project Manager), Prof. Dr. Kadir Pekmez, Prof. Dr. Dursun Ali Kose, Assoc. Dr. Gokhan Elmaci, Dr. Faculty Member Demet Özer, Dr. Faculty Member Zeliha Ertekin, Gökhan Özgenç, Arş. Gör. Dr. Okan Icten. (2018-)
• “Addition of Elemental Boron by Mechanochemical Method and Its Use in Catalytic Oxidation of Water”, TÜBİTAK-119Z860, Arş. Gör. Dr. Okan İçten (Project Manager) Prof. Dr. Birgül Karan (Project Advisor), Assoc. Dr. Gokhan Elmaci, Dr. Faculty Member Demet Özer, (2020-)

Completed Projects

• “Separation of Water with Iron Oxide-Manganese Oxide Nanocomposite Catalysts”, TUBITAK Rapid Support Project (113Z900), Birgül KARAN (Executive), Gökhan Elmacı (Scholarship) (2014-2015)
• “Preparation, Characterization and Molecular Dynamics Calculations of Bio-Inorganic Magnetic Nanocomposites Carrying Boron Neutron Capture Therapy (BNYT) Substances”, Birgül KARAN (Executive), Abidin Temel, Ahmet Nedim AY, Hacettepe University Scientific Research Project, 012 01 601 002, ( 2015)
• “Preparation and Characterization of Iron Oxide Layered Double Hydroxide Nano-Composites with Carborane Derivatives for BNCT Applications”, Ahmet Nedim Ay (Executive), Hande Akar, Birgül Karan, Hacettepe University Scientific Research Unit Research Project, 1529, (2016)
• “Preparation and Characterization of Biomolecule-Boron and Bioborate-Iron Oxide Nanosystems”, H.Ü. BAP Rapid Support Project (FHD-2015-7296), Prof. Dr. Birgül Karan (Project Manager), Assoc. Dr. Dursun Ali Köse, Res. See. Okan İçten (2015-2016)
• “Synthesis and Characterization of Manganese Ferrite Supported Transition Metal Arrested Birnesite Nanocomposite Catalysts for Catalytic Oxidation of Water”, H.Ü. BAP Rapid Support Project (FHD-2016-11201), Prof. Dr. Birgül Karan (Project Manager), Dr. Gökhan Elmacı, Gökhan Özgenç (2016-2018).
• “Synthesis of Magnetic Metal-Organic Lattice Structures (Fe3O4@Dex@MOF), Characterization and Investigation of Catalytic Efficiency in Oxidation Reactions”, H.Ü. BAP Rapid Support Project (FHD-2018-17552), Dr. Lecturer Demet Özer (Executive), Arş. Gör. Dr. Okan İçten (2018-2020).

Publications

•    Enhanced water oxidation performances of birnessite and magnetic birnessite nanocomposites by transition metal ion doping, G. Elmacı, G. Özgenç, P. Kurz, B. Zumreoglu-Karan, Sustainable Energy & Fuels, 2020, 4, 3157.
•    Layered double hydroxide–borate composites supported on magnetic nanoparticles: preparation, characterization and molecular dynamics simulations, A.N Ay, B Zumreoglu-Karan, A.G. Kalinichev, V. Rives, Journal of Porous Materials, 2020, 27, 735.
•    Facile synthesis of vanadium oxide supported on Fe2O3@ SiO2 composite: An effective catalyst for oxidative dehydrogenation reaction of tetrahydrocarbazole, D Ozer, O Icten, A Uzgoren-Baran, NA Oztas, Ceramics International, 2020, 46, 13762.
•    MIL-100 (Fe) metal–organic framework catalyzed oxidation of phenol revisited: dark-Fenton activity of the catalyst, D. Ozer, O. Icten, N. Altuntas-Oztas, B. Zumreoglu-Karan, Research on Chemical Intermediates, 2020, 46, 909.
•    Zwitterionic amino acids as precursors for nonmetal cation pentaborate salts, Ü Sizir, Ö Yurdakul, DA Köse, O Içten, Journal of the Chinese Chemical Society, 2020, 67, 1849.
•    Hydrothermal Synthesis of MIL-53 Catalyst for Liquid Phase Oxidation of Phenol, O İçten, D Özer, Hacettepe Journal of Biology and Chemistry, 2019, 47, 217.
•    Solution Combustion Synthesis of Iron Oxyborate (Fe3BO6), D Ozer, O Icten, Journal of the Turkish Chemical Society, Section A: Chemistry, 2019, 6, 97.
•    The mixed ligand complexes of Co (II), Ni (II), Cu (II) and Zn (II) with coumarilic acid/1, 10-phenanthroline, Ö Dağlı, DA Köse, O İçten, GA Avcı, O Şahin, Journal of Thermal Analysis and Calorimetry,2019, 136, 1467.
•    Gadolinium borate and iron oxide bioconjugates: Nanocomposites of next generation with multifunctional applications, O. Icten, D.A. Kose, S.J. Matissek, J.A. Misurelli, S.F. Elsawa, N. S. Hosmane, B. Zumreoglu-Karan, Materials Science and Engineering: C, 2018, 92, 317.
•    Fabrication and characterization of magnetite-gadolinium borate nanocomposites, O. Icten, DA Kose, B. Zumreoglu-Karan, Journal of Alloys and Compounds, 2017, 726, 437.
•    Magnetic nanocomposites of boron and vitamin C, O. Icten, N.S. Hosmane, D.A. Kose, B. Zumreoglu-Karan, New Journal of Chemistry, 2017, 41, 3646.
•    Liquid phase aerobic oxidation of benzyl alcohol by using manganese ferrite supported-manganese oxide nanocomposite catalyst, G. Elmaci, D Ozer, B. Zumreoglu-Karan - Catalysis Communications, 2017, 89, 56.
•    Carborane-layered double hydroxide nanohybrids for potential targeted-and magnetically targeted-BNCT applications, A.N. Ay, H. Akar, A. Zaulet, C. Viňas, F. Teixidor, B. Zümreoglu-Karan - Dalton Transactions, 2017, 46, 3303.
•    Magnetic nanocomposites of boron and vitamin C, O Icten, NS Hosmane, DA Kose, B Zumreoglu-Karan, New Journal of Chemistry, 2017, 41, 3646.
•    Production of Magnetic Nano‐bioconjugates via Ball Milling of Commercial Boron Powder with Biomolecules, O. Icten, N.S. Hosmane, D.A. Kose, B. Zumreoglu‐Karan - Zeitschrift für anorganische und Allgemeine Chemie, 2016, 642, 828.
•    Boron isotopic fractionation in aqueous boric acid solutions over synthetic minerals: Effect of layer and surface charge on fractionation factor, G. Elmaci, O. Icten, A.N. Ay, B. Zümreoglu-Karan - Applied Clay Science, 2015, 107, 117.
•    Water oxidation catalysis by birnessite@ iron oxide core–shell nanocomposites, G. Elmaci, C.E. Frey, P. Kurz, B. Zümreoğlu-Karan - Inorganic Chemistry, 2015, 54, 2734.
•    5-Fluorouracil intercalated iron oxide@ layered double hydroxide core-shell nano-composites with isotropic and anisotropic architectures for shape-selective drug delivery applications, G. Tuncelli, A.N. Ay, B. Zümreoglu-Karan - Materials Science and Engineering: C, 2015, 55, 562.

Links

About

Research Infrastructure

• Thermogravimetric/Differential Thermal analysis (Shimadzu DTG-60H)
• Differential Scanning Calorimetry Device (Shimadzu DSC-60)
• UV-3600 UV-VIS-NIR Spectrophotometer
• Parr 5500 High Pressure Reactor
• High Temperature Tube Furnace
• Vacuum Oven
• Rotary Evaporator

Researchers

•    Prof. Dr. Birgül KARAN
•    Prof. Dr. Ahmet Nedim Ay
•    Öğr. Gör. Dr. Okan İçten
•    Yüksek lisans öğrencisi Abdurrahman Mete Turgut
•    Doktora Öğrencisi, Ömer Yurdakul

Ongoing Projects

• “Development of Nano-Manganese Oxyborate Synthesis for Energy-Oriented Applications”, Comprehensive Research Project (2018-30-06-30-005), Supporting Organization: TENMAK-BOREN (National Boron Research Institute). prof. Dr. Birgül Karan (Project Manager), Prof. Dr. Kadir Pekmez, Prof. Dr. Dursun Ali Kose, Assoc. Dr. Gokhan Elmaci, Dr. Faculty Member Demet Özer, Dr. Faculty Member Zeliha Ertekin, Gökhan Özgenç, Arş. Gör. Dr. Okan Icten. (2018-)
• “Addition of Elemental Boron by Mechanochemical Method and Its Use in Catalytic Oxidation of Water”, TÜBİTAK-119Z860, Arş. Gör. Dr. Okan İçten (Project Manager) Prof. Dr. Birgül Karan (Project Advisor), Assoc. Dr. Gokhan Elmaci, Dr. Faculty Member Demet Özer, (2020-)

Completed Projects

• “Separation of Water with Iron Oxide-Manganese Oxide Nanocomposite Catalysts”, TUBITAK Rapid Support Project (113Z900), Birgül KARAN (Executive), Gökhan Elmacı (Scholarship) (2014-2015)
• “Preparation, Characterization and Molecular Dynamics Calculations of Bio-Inorganic Magnetic Nanocomposites Carrying Boron Neutron Capture Therapy (BNYT) Substances”, Birgül KARAN (Executive), Abidin Temel, Ahmet Nedim AY, Hacettepe University Scientific Research Project, 012 01 601 002, ( 2015)
• “Preparation and Characterization of Iron Oxide Layered Double Hydroxide Nano-Composites with Carborane Derivatives for BNCT Applications”, Ahmet Nedim Ay (Executive), Hande Akar, Birgül Karan, Hacettepe University Scientific Research Unit Research Project, 1529, (2016)
• “Preparation and Characterization of Biomolecule-Boron and Bioborate-Iron Oxide Nanosystems”, H.Ü. BAP Rapid Support Project (FHD-2015-7296), Prof. Dr. Birgül Karan (Project Manager), Assoc. Dr. Dursun Ali Köse, Res. See. Okan İçten (2015-2016)
• “Synthesis and Characterization of Manganese Ferrite Supported Transition Metal Arrested Birnesite Nanocomposite Catalysts for Catalytic Oxidation of Water”, H.Ü. BAP Rapid Support Project (FHD-2016-11201), Prof. Dr. Birgül Karan (Project Manager), Dr. Gökhan Elmacı, Gökhan Özgenç (2016-2018).
• “Synthesis of Magnetic Metal-Organic Lattice Structures (Fe3O4@Dex@MOF), Characterization and Investigation of Catalytic Efficiency in Oxidation Reactions”, H.Ü. BAP Rapid Support Project (FHD-2018-17552), Dr. Lecturer Demet Özer (Executive), Arş. Gör. Dr. Okan İçten (2018-2020).

Publications

•    Enhanced water oxidation performances of birnessite and magnetic birnessite nanocomposites by transition metal ion doping, G. Elmacı, G. Özgenç, P. Kurz, B. Zumreoglu-Karan, Sustainable Energy & Fuels, 2020, 4, 3157.
•    Layered double hydroxide–borate composites supported on magnetic nanoparticles: preparation, characterization and molecular dynamics simulations, A.N Ay, B Zumreoglu-Karan, A.G. Kalinichev, V. Rives, Journal of Porous Materials, 2020, 27, 735.
•    Facile synthesis of vanadium oxide supported on Fe2O3@ SiO2 composite: An effective catalyst for oxidative dehydrogenation reaction of tetrahydrocarbazole, D Ozer, O Icten, A Uzgoren-Baran, NA Oztas, Ceramics International, 2020, 46, 13762.
•    MIL-100 (Fe) metal–organic framework catalyzed oxidation of phenol revisited: dark-Fenton activity of the catalyst, D. Ozer, O. Icten, N. Altuntas-Oztas, B. Zumreoglu-Karan, Research on Chemical Intermediates, 2020, 46, 909.
•    Zwitterionic amino acids as precursors for nonmetal cation pentaborate salts, Ü Sizir, Ö Yurdakul, DA Köse, O Içten, Journal of the Chinese Chemical Society, 2020, 67, 1849.
•    Hydrothermal Synthesis of MIL-53 Catalyst for Liquid Phase Oxidation of Phenol, O İçten, D Özer, Hacettepe Journal of Biology and Chemistry, 2019, 47, 217.
•    Solution Combustion Synthesis of Iron Oxyborate (Fe3BO6), D Ozer, O Icten, Journal of the Turkish Chemical Society, Section A: Chemistry, 2019, 6, 97.
•    The mixed ligand complexes of Co (II), Ni (II), Cu (II) and Zn (II) with coumarilic acid/1, 10-phenanthroline, Ö Dağlı, DA Köse, O İçten, GA Avcı, O Şahin, Journal of Thermal Analysis and Calorimetry,2019, 136, 1467.
•    Gadolinium borate and iron oxide bioconjugates: Nanocomposites of next generation with multifunctional applications, O. Icten, D.A. Kose, S.J. Matissek, J.A. Misurelli, S.F. Elsawa, N. S. Hosmane, B. Zumreoglu-Karan, Materials Science and Engineering: C, 2018, 92, 317.
•    Fabrication and characterization of magnetite-gadolinium borate nanocomposites, O. Icten, DA Kose, B. Zumreoglu-Karan, Journal of Alloys and Compounds, 2017, 726, 437.
•    Magnetic nanocomposites of boron and vitamin C, O. Icten, N.S. Hosmane, D.A. Kose, B. Zumreoglu-Karan, New Journal of Chemistry, 2017, 41, 3646.
•    Liquid phase aerobic oxidation of benzyl alcohol by using manganese ferrite supported-manganese oxide nanocomposite catalyst, G. Elmaci, D Ozer, B. Zumreoglu-Karan - Catalysis Communications, 2017, 89, 56.
•    Carborane-layered double hydroxide nanohybrids for potential targeted-and magnetically targeted-BNCT applications, A.N. Ay, H. Akar, A. Zaulet, C. Viňas, F. Teixidor, B. Zümreoglu-Karan - Dalton Transactions, 2017, 46, 3303.
•    Magnetic nanocomposites of boron and vitamin C, O Icten, NS Hosmane, DA Kose, B Zumreoglu-Karan, New Journal of Chemistry, 2017, 41, 3646.
•    Production of Magnetic Nano‐bioconjugates via Ball Milling of Commercial Boron Powder with Biomolecules, O. Icten, N.S. Hosmane, D.A. Kose, B. Zumreoglu‐Karan - Zeitschrift für anorganische und Allgemeine Chemie, 2016, 642, 828.
•    Boron isotopic fractionation in aqueous boric acid solutions over synthetic minerals: Effect of layer and surface charge on fractionation factor, G. Elmaci, O. Icten, A.N. Ay, B. Zümreoglu-Karan - Applied Clay Science, 2015, 107, 117.
•    Water oxidation catalysis by birnessite@ iron oxide core–shell nanocomposites, G. Elmaci, C.E. Frey, P. Kurz, B. Zümreoğlu-Karan - Inorganic Chemistry, 2015, 54, 2734.
•    5-Fluorouracil intercalated iron oxide@ layered double hydroxide core-shell nano-composites with isotropic and anisotropic architectures for shape-selective drug delivery applications, G. Tuncelli, A.N. Ay, B. Zümreoglu-Karan - Materials Science and Engineering: C, 2015, 55, 562.

Links